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PFS StandardDemon Bone TilesItem 2+

Rare Catalyst Consumable Magical Unholy 
Source Rival Academies pg. 111
Usage held in 1 hand; Bulk L
Activate Cast a Spell (add 1 action)
These bones from different types of demons can be used to form temporary barriers. When you crush the bone fragments and blow the resulting dust around yourself as you cast shield, the shield appears as a bone bulwark shaped like the demon’s face.

When use Shield Block with the spell, the barrier explodes into many bone fragments. The shards cause persistent bleed damage to each creature adjacent to you that fails a Reflex save at the listed DC. This persistent bleed damage is unholy and can be stopped with an Interact action to remove the shards.

PFS StandardPusk Bone TilesItem 2

Source Rival Academies pg. 111
Price 7 gp
The persistent bleed damage is 1d4, and the save DC is 16.

PFS StandardBrimorak Bone TilesItem 5

Source Rival Academies pg. 111
Price 28 gp
The persistent bleed damage is 1d6, and the save DC is 20.

PFS StandardSeraptis Bone TilesItem 15

Source Rival Academies pg. 111
Price 1,200 gp
The persistent bleed damage is 2d8, and the save DC is 34.